多巴胺在聚3，4-吡啶二羧酸修饰电极上的电化学行为及其测定   总被引：10，自引：0，他引：10  

袁倬斌  吕元琦  邬春华 《岩矿测试》2003,22(4):258-262

制备了聚3,4-吡啶二羧酸修饰电极,研究了多巴胺在修饰电极上的电化学行为。结果表明聚3,4-吡啶二羧酸聚合物膜对多巴胺的氧化具有明显的催化作用,并且可以消除抗坏血酸对多巴胺测定中的干扰。多巴胺的浓度在2.0×10-6～4.0×10-5mol/L内与其氧化电流呈线性关系,相对标准偏差为3.2%(n=10),检出限为8.0×10-8mol/L。将该修饰电极用于分析模拟样品和注射液样品中的多巴胺,分析结果表明,该修饰电极有望用于实际样品分析。  相似文献   

Mid-holocene climate change in Lake Bosumtwi, Ghana     

James Russell  Michael R TalbotBrian J Haskell 《Quaternary Research》2003,60(2):133-141

Lake Bosumtwi is one of the most widely studied palaeoclimate archives in West Africa. Results from numerous AMS ¹⁴C dates of samples from four piston cores from Lake Bosumtwi show that an abrupt sedimentary transition from a mid-Holocene sapropel to calcareous laminated muds occurred at about 3200 cal yr B.P. High-resolution analyses of the nitrogen isotopic composition of organic matter across this transition confirm its abrupt nature, and suggest that the change may signal a step toward increased aridity and intensified surface winds that affected western equatorial Africa from Ghana to the Congo basin. Northern and Eastern Africa experienced a similar abrupt shift toward aridity during the late Holocene, but at about 5000 cal yr B.P., a difference in timing that illustrates the regional nature of climate changes during the Holocene and the importance of feedback mechanisms in regulating Holocene climate variability. Furthermore, an abrupt change at about 3000 cal yr B.P. occurs at several sites adjacent to the tropical and subtropical Atlantic, which may hint at major changes in the surface temperatures of the tropical Atlantic and/or Pacific at this time.  相似文献   

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development     

G. Chi  P. S. Giles  M. A. Williamson  D. Lavoie  R. Bertrand 《Journal of Geochemical Exploration》2003,80(2-3):171-191

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.  相似文献   

Oxygen isotope composition and geothermometry of granulite to greenschist facies metamorphic rocks: a study from the Neoproterozoic collision-related nappe system, south of São Francisco Craton, SE Brazil     

Maria da Glria M. Garcia  Mrio C. Campos Neto  Anthony E. Fallick 《Journal of South American Earth Sciences》2003,15(8):871-883

Oxygen isotope studies were carried out across units of a Neoproterozoic nappe system, south of São Francisco Craton. A temperature decrease toward the base of the system is found, consistent with a previously recognized inverted metamorphic pattern. The tectonic contact of the basal unit and the reworked southern São Francisco craton show a steep temperature gradient, suggesting that low temperature thrusting acted as the dominant tectonic process. The contrasts between the δ¹⁸O values of the Três Pontas-Varginha and Carmo da Cachoeira nappes and the differences among the samples and minerals are consistent with the preservation of sedimentary isotopic composition during metamorphism. The small differences in the δ¹⁸O values between the undeformed and the deformed calc-silicate samples (1.6‰) suggest that the δ¹⁸O value of mylonitization fluids was close to that which equilibrated with the metamorphic assemblage. The distinct δ¹⁸O values of metapelitic and calc-silicate samples and the great temperature difference from one type to the other indicate that no large-scale fluid interaction processes occurred during metamorphism. Oxygen isotopic estimations of both Três Pontas-Varginha undeformed rocks and Carmo da Cachoeira unaltered equivalents indicate δ¹⁸O values of up to 18‰. Comparison between these values and those from the ‘basement’ orthogneisses (8.3–8.5‰) indicates the latter are not sources for the metapelites.  相似文献   

Hydrochemical and isotopic characteristics of groundwater in the Souss Upstream Basin, southwestern Morocco     

K. Dindane  L. Bouchaou  Y. Hsissou  M. Krimissa   《Journal of African Earth Sciences》2003,36(4):315-327

Heterogeneous shallow Plio-Quaternary formations of the Souss Plain represent the most important aquifer in southern High Atlas Mountains in Morocco. The present work was conducted in the Souss Upstream Basin to identify the chemical characteristics and the origin of groundwater in an aquifer under semi-arid climate. Isotopic and hydrochemical compositions combined with geological and hydrogeological data were used for this purpose. The total dissolved solids vary from 239 to 997 mg l⁻¹, and the following groundwater types are recognized: Ca²⁺–Mg²⁺–HCO₃⁻, Ca²⁺–Mg²⁺–SO₄²⁻ and Ca²⁺–Mg²⁺–Cl⁻. The groundwater is saturated and slightly supersaturated with respect to carbonate minerals and undersaturated with respect to evaporite minerals, which means that the groundwater composition is largely controlled by the dissolution of carbonate rocks known in the basin. The isotopic contents of groundwaters ranged from −8‰ to −5.2‰ for δ¹⁸O, from −52‰ to −34‰ for δD, and from 0 to 5.5 TU for tritium. The hydrogen (δD) and oxygen (δ¹⁸O) isotope signatures reveal a significant infiltration before evaporation takes place, indicating a major recharge directly from fractures in the crystalline and limestone formations of Atlas Mountains (above 800 m a.s.l.) and infiltration of surface water in the alluvial cones at the border of the Atlas basins. The very low tritium values suggest that the groundwater recharge follows a long flow path and a mixing between old and modern water is shown. However, a slight evaporation effect is noted in the southern part of the basin close to the Anti-Atlas Mountains.  相似文献   

Dinosaur coprolites from the Late Cretaceous (Maastrichtian) Lameta Formation of India: isotopic and other markers suggesting a C₃plant diet     

Prosenjit Ghosh  S. K. Bhattacharya  Ashok Sahni  R. K. Kar  D. M. Mohabey  K. Ambwani 《Cretaceous Research》2003,24(6):743-750

A single locality of the Late Cretaceous (Maastrichtian) Lameta Formation at Pisdura in Central India has yielded a large number of coprolites attributed to titanosaurian dinosaurs. Internally the coprolites are dark grey and contain abundant plant tissues and other organic materials. The plant tissues are mostly of gymnospermous origin. In addition, remains of bacterial colonies, fungal spores and algae are seen in the macerated fraction under scanning electron microscope. The dark grey appearance is probably attributable to fine-grained organic matter within voids in tracheids or xylem. The average ¹³C/¹²C ratio of the organic matter in the coprolites is -24‰ (relative to PDB) suggesting that plants of C₃type were the main diet of their producers. A comparison of δ¹⁵N value (about 4‰ w.r.t. air) of the coprolites with that of faecal matter of modern herbivores and carnivores suggests that gut fermentation may not have been an active mechanism in the digestion process of titanosaurs.  相似文献   

Origin and Formational Environment of Noda-Tamagawa Manganese Ore, Northeast Japan: Constraints from Isotopic Studies     

Mohammed El Rhazi  Ken-ichiro Hayashi 《Chemie der Erde / Geochemistry》2003,63(2):149-162

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Relationship of topography to surface water chemistry with particular focus on nitrogen and organic carbon solutes within a forested watershed in Hokkaido,Japan     

Akiko Ogawa  Hideaki Shibata  Kei Suzuki  Myron J. Mitchell  Yoshiyuki Ikegami 《水文研究》2006,20(2):251-265

We studied the relationships between streamwater chemistry and the topography of subcatchments in the Dorokawa watershed in Hokkaido Island, northern Japan, to examine the use of topography as a predictor of streamwater chemistry in a watershed with relatively moderate terrain compared with other regions of Japan. Topographic characteristics of the Dorokawa watershed and its subcatchments were expressed as topographic index (TI) values, which ranged from 4·5 to 20·4 for individual grid cells (50 × 50 m²), but averaged from 6·4 to 7·4 for the 20 subcatchments. Streamwater samples for chemical analyses were collected four times between June and October 2002 from 20 locations in the watershed. The pH of water that passed through the watershed increased from ～5·0 to 7·0, with major increases in Na⁺ and Ca²⁺ and marked decreases in NO₃^? and SO . Distinctive spatial patterns were observed for dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NO₃^? concentrations of streamwater across the watershed. Statistical analyses indicated significant linear relationships between the average TI values of subcatchments and DOC, DON, and NO₃^? concentrations. Furthermore, the proportion of DOC in streamwaters in the wet season increased with TI values relative to other nitrogen species, whereas NO₃^? concentrations decreased with TI. The gradients of soil wetness and the presence of wetlands explained many of the observed spatial and temporal patterns of DOC, DON, and NO₃^? concentrations in the surface waters of the Dorokawa watershed. Our results suggest that the TI is especially useful for predicting the spatial distribution of DOC, DON and NO₃^? in the surface waters of Hokkaido, where topographical relief is moderate and wetlands more common than in other regions of Japan. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Geochemical Constraints on the Origin of Volcanic Rocks from the Andean Northern Volcanic Zone, Ecuador   总被引：2，自引：0，他引：2  

BRYANT  J. A.; YOGODZINSKI  G. M.; HALL  M. L.; LEWICKI  J. L.; BAILEY  D. G. 《Journal of Petrology》2006,47(6):1147-1175

Whole-rock geochemical data on basaltic to rhyolitic samplesfrom 12 volcanic centers are used to constrain the role of continentalcrust in the genesis of magmas formed beneath the anomalouslywide subduction-related volcanic arc in Ecuador. Relativelyhomogeneous, mantle-like, isotopic compositions across the arcimply that the parental magmas in Ecuador were produced largelywithin the mantle wedge above the subduction zone and not byextensive melting of crustal rocks similar to those upon whichthe volcanoes were built. Cross-arc changes in ¹⁴³Nd/¹⁴⁴Nd and7/4Pb are interpreted to result from assimilation of geochemicallymature continental crust, especially in the main arc area, 330–360km from the trench. Mixing calculations limit the quantity ofassimilated crust to less than 10%. Most andesites and dacitesin Ecuador have adakite-like trace element characteristics (e.g.Y <18 ppm, Yb <2 ppm, La/Yb >20, Sr/Y >40). Availablewhole-rock data do not provide a clear basis for distinguishingbetween slab-melting and deep crustal fractionation models forthe genesis of Ecuador adakites; published data highlightinggeochemical evolution within individual volcanoes, and in magmaticrocks produced throughout Ecuador since the Eocene, appear tosupport the deep fractionation model for the genesis of mostevolved Ecuadoran lavas. A subset of andesites, which displaya combination of high Sr (>900 ppm), Nd >4·1 and7/4Pb <6·0, appear to be the best candidates amongEcuador lavas for slab-melts associated with the subductionof the relatively young, over-thickened, oceanic crust of theCarnegie Ridge. KEY WORDS: andesite; Ecuador; trace elements; isotopes; adakite  相似文献   

Origin and Source Evolution of the Leucite Hills Lamproites: Evidence from Sr-Nd-Pb-O Isotopic Compositions   总被引：2，自引：0，他引：2  

MIRNEJAD  H.; BELL  K. 《Journal of Petrology》2006,47(12):2463-2489

Whole-rock major and trace element and O, Sr, Nd and Pb isotopicdata are reported for 3·0–0·89 Ma lamproitesfrom the Leucite Hills, Wyoming, USA. The two main groups oflamproites, madupitic lamproites and phlogopite lamproites,are geochemically distinct and cannot be related to one anotherby either fractional crystallization or crustal contamination.It seems likely that the geochemical differences between thesetwo rock types are related to variations in source mineralogyand depth of partial melting. The high Mg-number and large ionlithophile element abundances and negative Nd values of thelamproites indicate a mantle source that has experienced stagesof both depletion and enrichment. The negative Nb, Ta and Tianomalies in mantle-normalized trace element diagrams and lowtime-integrated U/Pb, Rb/Sr and Sm/Nd ratios of both lamproitegroups and other Cenozoic igneous rocks from the Wyoming ArcheanProvince indicate an ancient metasomatic enrichment (>1·0Ga) of the mantle source associated with the subduction of carbonate-bearingsediments. Other chemical characteristics of the Leucite Hillslamproites, especially their high K₂O and volatile contents,are attributed to more recent metasomatism (<100 Ma) involvinginflux from upwelling mantle during back-arc extension or plumeactivity. KEY WORDS: isotopes; lamproites; metasomatism; Leucite Hills; Wyoming  相似文献